The longer spilled oil lingers in freshwater, the more persistent compounds it produces
Weathering assessments of polar and non-polar petroleum components using Orbitrap and Fourier Transform Ion Cyclotron Resonance Mass Spectrometry.
Oil is an important resource for many industries, but it can lead to serious environmental damage when accidentally spilled. While large oil spills are highly publicized, every year there are many smaller-scale spills into lakes, rivers and oceans. And, according to research published in ACS’ Energy & Fuels, the longer that oil remains in freshwater, the more chemical changes it undergoes, creating products that can persist in the environment.
Approximately 600,000 gallons of oil were accidentally spilled into the environment in 2023, according to the International Tanker Owners Pollution Federation, a group that monitors oil spills. This figure represents ocean spills as well as freshwater spills in rivers and lakes. Over time, this oil weathers and undergoes a variety of chemical transformations, which could make compounds that are more soluble in water and stick around longer. Weathering in salt water is reasonably well understood, but what happens to oil in freshwater is still being investigated. So, Dena McMartin and colleagues investigated the chemical changes that could happen to that oil as it sits in rivers and lakes.
The team simulated a freshwater oil spill in the laboratory by combining water and river sediment collected directly from the North Saskatchewan River in Alberta, Canada, in a tank and then adding conventional crude oil obtained from a pipeline operator in Alberta. The test was carried out at around 75 degrees Fahrenheit for 56 days. Water samples were taken at multiple time points from the simulated spill and subjected to Fourier-transform ion cyclotron resonance (FT-ICR) and ion trap mass spectrometry, which provided detailed information into the chemical makeup of these complicated mixtures.
Researchers concluded that as the oil weathered, more and more oxygen atoms were incorporated into some compounds, causing them to become more persistent in water. As a result, higher concentrations of the oxygen-loaded chemicals could build up, potentially increasing the impact on aquatic organisms. This increase in oxygen atoms was observed for sulfur oxide compounds, along with some other classes of compounds present in the crude oil mixture. McMartin and team members say these results emphasize the importance of rapid responses to oil spills and could help set benchmarks for longer-term remediation efforts.
Original publication
Chukwuemeka Ajaero, Ian Vander Meulen, Nicole E. Heshka, Qin Xin, Dena W. McMartin, Kerry M. Peru, Huan Chen, Amy M. McKenna, Kiaura Reed, John V. Headley; "Evaluations of Weathering of Polar and Nonpolar Petroleum Components in a Simulated Freshwater–Oil Spill by Orbitrap and Fourier Transform Ion Cyclotron Resonance Mass Spectrometry"; Energy & Fuels, Volume 38, 2024-4-8
Other news from the department science
![[Fe]-hydrogenase catalysis visualized using para-hydrogen-enhanced nuclear magnetic resonance spectroscopy](https://img.chemie.de/Portal/News/675fd46b9b54f_sBuG8s4sS.png?tr=w-712,h-534,cm-extract,x-0,y-16:n-xl)
Get the analytics and lab tech industry in your inbox
From now on, don't miss a thing: Our newsletter for analytics and lab technology brings you up to date every Tuesday. The latest industry news, product highlights and innovations - compact and easy to understand in your inbox. Researched by us so you don't have to.
Most read news
More news from our other portals
See the theme worlds for related content
Topic World Spectroscopy
Investigation with spectroscopy gives us unique insights into the composition and structure of materials. From UV-Vis spectroscopy to infrared and Raman spectroscopy to fluorescence and atomic absorption spectroscopy, spectroscopy offers us a wide range of analytical techniques to precisely characterize substances. Immerse yourself in the fascinating world of spectroscopy!
Topic World Spectroscopy
Investigation with spectroscopy gives us unique insights into the composition and structure of materials. From UV-Vis spectroscopy to infrared and Raman spectroscopy to fluorescence and atomic absorption spectroscopy, spectroscopy offers us a wide range of analytical techniques to precisely characterize substances. Immerse yourself in the fascinating world of spectroscopy!
Topic World Mass Spectrometry
Mass spectrometry enables us to detect and identify molecules and reveal their structure. Whether in chemistry, biochemistry or forensics - mass spectrometry opens up unexpected insights into the composition of our world. Immerse yourself in the fascinating world of mass spectrometry!
Topic World Mass Spectrometry
Mass spectrometry enables us to detect and identify molecules and reveal their structure. Whether in chemistry, biochemistry or forensics - mass spectrometry opens up unexpected insights into the composition of our world. Immerse yourself in the fascinating world of mass spectrometry!
